کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
7996411 1516207 2016 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
One-step fabrication of Fe-Si-O/carbon nanotube composite anode material with excellent high-rate long-term cycling stability
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد فلزات و آلیاژها
پیش نمایش صفحه اول مقاله
One-step fabrication of Fe-Si-O/carbon nanotube composite anode material with excellent high-rate long-term cycling stability
چکیده انگلیسی
The composite of Fe2SiO4 with carbon nanotubes, Fe3O4 and Fe3C are fabricated by a simple one-step reaction between ferrocene and tetraethyl orthosilicate. The composite utilized as anode material for Li-ion storage exhibits ever-increasing capacities when cycled at a current density of 100 mA g−1, and after 280 cycles, a stable capacity of 588 mAh g−1 is achieved. When cycled at 200, 400, 800 and 1600 mA g−1, the reversible capacities are 364, 323, 281, 235, and 186 mAh g−1, respectively. Even cycled at 500 mA g−1, a reversible capacity of 350 mAh g−1 is retained after 600 cycles. The excellent performance is much superior to that of the carbon-coated Fe3O4 prepared under the similar conditions. The outstanding performance associates significantly with the electronic conductivity of in-situ formed carbon nanotubes with uniform dispersion and Fe3C coated on the Fe2SiO4 nanoparticles, as well as the formation of lithium silicates to act as solid electrolyte for enhancing the ionic conductivity.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Alloys and Compounds - Volume 686, 25 November 2016, Pages 318-325
نویسندگان
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