کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7997215 | 1516211 | 2016 | 23 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Pt nanoparticles anchored on Nb2O5 and carbon fibers as an enhanced performance catalyst for methanol oxidation
دانلود مقاله + سفارش ترجمه
دانلود مقاله ISI انگلیسی
رایگان برای ایرانیان
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
فلزات و آلیاژها
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
In this work, Nb2O5 and carbon composite nanofibers (Nb2O5/C) was prepared by a facile electrospinning method, and was employed as the electrochemical support of Pt nanoparticles for methanol oxidation reaction. The obtained Nb2O5/C and Pt/Nb2O5/C was characterized by a series of materials characterization technical including X-ray diffraction (XRD), scan and transmission electron microscopies (SEM and TEM) and X-ray photoelectron spectroscopy (XPS). XRD results showed that Nb2O5 in Nb2O5/C exhibited a smaller lattice constant compared with pure Nb2O5, indicating that Nb2O5 in Nb2O5/C composite nanofibers was partially reduced. The TEM images showed that the nano Pt particles with an average size of 3Â nm was uniformly deposited on Nb2O5/C nanofiber support. The enhanced electrochemical performance toward MOR could be ascribed to the enhanced electrical conductivity of nano Nb2O5/C nanofibers and the strong connection between Pt and Nb2O5/C support, which can weak the binding energy between Pt and CO-intermediate and providing the rich active OH species on Nb2O5/C support.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Alloys and Compounds - Volume 682, 15 October 2016, Pages 584-589
Journal: Journal of Alloys and Compounds - Volume 682, 15 October 2016, Pages 584-589
نویسندگان
Bitao Liu, Huiqiang Wang, Yun Chen, Jun Wang, Lingling Peng, Lu Li,