کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7998579 | 1516249 | 2015 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Magnetocaloric refrigerant with wide operating temperature range based on Mn5âxGe3(Co,Fe)x composite
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موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
فلزات و آلیاژها
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چکیده انگلیسی
The Curie temperature of Mn5Ge3 was raised or lowered by alloying the compound with Fe or Co; hence, the temperature at which maximum magnetocaloric effect manifested was easily manipulated by forming Mn5âxGe3(Co,Fe)x alloys to ultimately develop a composite magnetic refrigerant consisting of multiple Mn5Ge3 - based alloys. The composite refrigerant was designed to produce a table-like ÎSM-T curve and to maximize the RC value near room temperature. Linear combination of the ÎSM-T curves for the constituent materials showed that a composite composed of physical mixture of four different Mn5Ge3-based compounds: Mn5Ge3, Mn5.1Ge2.9, Mn4.75Co0.25Ge3 and Mn4.75Fe0.25Ge3, generated an optimal ÎSM-T curve with a table-like shape. The composite refrigerant with refrigeration capacity of 52Â JÂ kgâ1, peak entropy change at 300Â K, and operating temperature range of 45Â K under ÎHÂ =Â 10Â kOe was suitable for room-temperature magnetic refrigeration. Moreover, by changing the relative fraction of each constituent material in the composite, it was shown that the operating temperature range could be fine-tuned as needed. The calculated ÎSM-T curve for the composite refrigerant by linear combination reasonably well matched the experimental ÎSM-T curve estimated from the M-H curves of the composite refrigerant, suggesting that the simple linear combination of the experimental ÎSM-T curves can be used to predict the performance of the composite magnetic refrigerants whose MCE was originated from the second order magnetic transition. In conclusion, being rare-earth free and lacking thermal or magnetic hysteresis, the Mn5Ge3 - based composite can be a competitive candidate magnetic refrigerant material operating at room temperature in terms of both economy and reliability compared to the giant MCE materials such as Gd - based intermetallic compounds or Heusler alloys.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Alloys and Compounds - Volume 644, 25 September 2015, Pages 464-469
Journal: Journal of Alloys and Compounds - Volume 644, 25 September 2015, Pages 464-469
نویسندگان
Yongdeok Kim, Ki Hoon Kang, Ju Hwan Kim, Eun Jeong Kim, Kwangseok Choi, Won Bae Han, Hee-Soo Kim, Yoong Oh, Chong Seung Yoon,