کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7998974 | 1516254 | 2015 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Synthesis of reduced graphene oxide-iron nanoparticles with superior enzyme-mimetic activity for biosensing application
ترجمه فارسی عنوان
سنتز کاهش نانوذرات آهن اکسید گرافین با عملکرد آنزیم-مینیمم برتر برای کاربرد بیوسنسینس
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
فلزات و آلیاژها
چکیده انگلیسی
Development of enzyme-mimetic catalysts with sustainability and environmental benignancy has gained considerable attention with the growing demands for large-scale applications in recent years. Here, we demonstrate that the reduced graphene oxide (RGO)-iron nanoparticles (INs) can be utilized as the highly active and cost-effective enzyme-mimetic catalysts for the first time, which have been successfully synthesized by a facile iron-self-catalysis process at room temperature. Benefitting from synergetic effects between RGO and INs, the RGO-INs could efficiently catalyze the oxidization of 3,3â²,5,5â²-tetramethylbenzidine (TMB) in the presence of H2O2 to produce a typical color reaction, showing the much better peroxidase-like activity than that of each individual part. The mechanistic insight into the enhanced peroxidase-like activity of the RGO-INs was investigated systematically. On the basis of the enzyme-mimetic activity of the RGO-INs, the simple, sensitive, selective and cost-effective colorimetric assays for the detection of hydrogen peroxide and glucose with naked eyes were successfully established. The RGO-INs showed several prominent advantages, such as facile preparation, low cost, tunability in catalytic activity, and low detection limit, over natural peroxidase or other nanomaterial-based alternatives, holding great potential as enzymatic mimics for biosensing applications.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Alloys and Compounds - Volume 639, 5 August 2015, Pages 470-477
Journal: Journal of Alloys and Compounds - Volume 639, 5 August 2015, Pages 470-477
نویسندگان
Lili Li, Chunmei Zeng, Lunhong Ai, Jing Jiang,