کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
8000055 | 1516272 | 2015 | 24 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Hydrogen absorption-desorption cycle durability of SmMgNi4
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
فلزات و آلیاژها
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چکیده انگلیسی
The reversible hydrogen storage capacity and structural features against cycle numbers of SmMgNi4 compound prepared by the combination of ball-milling with sintering are investigated systematically in this work. It is found that the structure of SmMgNi4 with an exchange between Sm and Mg by 13% has a good stability without occurrence of hydrogen-induced amorphization and phase decomposition upon multiple cycling. However, about 16% capacity loss is still observed at the early stages of hydrogen ab-/desorption cycles at 298Â K. The increase in lattice strain caused by the accumulation of dislocations is believed to be responsible for the capacity degradation of SmMgNi4.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Alloys and Compounds - Volume 621, 5 February 2015, Pages 42-46
Journal: Journal of Alloys and Compounds - Volume 621, 5 February 2015, Pages 42-46
نویسندگان
Z.L. Chen, T.Z. Si, Q.A. Zhang,