کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
8000655 | 1516274 | 2015 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
An erbium(III)-based NIR emitter with a highly conjugated β-diketonate for blue-region sensitization
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
فلزات و آلیاژها
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چکیده انگلیسی
The sensitization of lanthanide complexes in the visible region is of particular interest for practical applications such as labeling, biological analysis and optoelectronics. A visible-light sensitized Er3+ complex based on the use of a highly conjugated β-diketonate (1,3-di(2-naphthyl)-1,3-propanedione, Hdnm) and 5-nitro-1,10-phenanthroline (5NO2phen) as an ancillary ligand, [Er(dnm)3(5NO2phen)], has been synthesized, fully characterized and its photophysical properties have been investigated. Suitably expanded Ï-conjugation in the complex molecule makes the excitation window red-shifted to the visible region (up to 550 nm). Efficient energy transfer by antenna effect results in 1.53 μm emission from the Er3+ ion.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Alloys and Compounds - Volume 619, 15 January 2015, Pages 553-559
Journal: Journal of Alloys and Compounds - Volume 619, 15 January 2015, Pages 553-559
نویسندگان
P. MartÃn-Ramos, I.R. MartÃn, F. Lahoz, S. Hernández-Navarro, P.S. Pereira da Silva, I. Hernández, V. LavÃn, M. Ramos Silva,