کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
8018368 1517236 2015 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Enhancement of the thermoelectric properties of BaCu2Se2 by potassium doping
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد فناوری نانو (نانو تکنولوژی)
پیش نمایش صفحه اول مقاله
Enhancement of the thermoelectric properties of BaCu2Se2 by potassium doping
چکیده انگلیسی
Layered compounds play an important role in thermoelectric materials exploration, as their thermal and electrical conductivities could be affected by different layers. Herein, we have synthesized a new layered Ba0.7K0.3Cu2Se2 phase with the ThCr2Si2 structure through 30% K doping on the Ba sites in the pristine orthorhombic BaCu2Se2. The layered Ba0.7K0.3Cu2Se2 exhibits intrinsically low lattice thermal conductivity due to its extremely short phonon mean free path. Ba0.7K0.3Cu2Se2 also features high hole mobility and reasonable Seebeck coefficient at high doping levels. The enhancement of electrical conductivity is mainly ascribed to the increase of the hole concentration and the unchanged high hole mobility. As a result, the peak ZT of Ba0.7K0.3Cu2Se2 reaches 0.32 at 800 K, which is of significance by comparing to its undoped BaCu2Se2 counterpart.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Materials Letters - Volume 152, 1 August 2015, Pages 117-120
نویسندگان
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