کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
8046057 1519031 2018 10 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Influence of the synthetic conditions on the composition, morphology of CuMgAl hydrotalcites and their use as catalytic precursor in diesel soot combustion reactions
موضوعات مرتبط
مهندسی و علوم پایه علوم زمین و سیارات ژئوشیمی و پترولوژی
پیش نمایش صفحه اول مقاله
Influence of the synthetic conditions on the composition, morphology of CuMgAl hydrotalcites and their use as catalytic precursor in diesel soot combustion reactions
چکیده انگلیسی
In this work, a series of Cu-Mg-Al hydrotalcites and the oxide mixture obtained by their calcination at 600 °C were synthesized by coprecipitation from metal nitrates. The effect of the coprecipitation temperature of the precursor on the structure and texture of these materials was investigated. The solids were characterised by inductively coupled plasma (ICP), atomic absorption spectrophotometry (AAS), an energy dispersive spectrometer (EDAX), thermogravimetric analysis (TGA-DTA), X-ray diffraction (XRD), scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), and Fourier transform infrared spectroscopy (FTIR). It has been studied the activity of these solids as catalysts for diesel soot combustion. The materials are formed by nanoparticles, and the coprecipitation temperature has influence in the morphology of hydrotalcites. Moreover, the catalytic performance of calcinated solids is influenced by the synthesis conditions. A low temperature coprecipitation is beneficial for the diesel soot combustion. In this sense, the solid obtained by coprecipitacion at 40 °C shows the best catalytic activity (Tmax = 375 °C). This catalyst contains cooper oxides, potassium and nitrate ions which can acts as promoters of the soot combustion. The studied solids showed activity and high resistance to the deactivation caused by hydro-treatment.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Applied Clay Science - Volume 157, 1 June 2018, Pages 148-157
نویسندگان
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