کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
8124920 1522775 2018 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
EPR study of spectra transformations of the intrinsic vanadyl-porphyrin complexes in heavy crude oils with temperature to probe the asphaltenes' aggregation
موضوعات مرتبط
مهندسی و علوم پایه علوم زمین و سیارات زمین شناسی اقتصادی
پیش نمایش صفحه اول مقاله
EPR study of spectra transformations of the intrinsic vanadyl-porphyrin complexes in heavy crude oils with temperature to probe the asphaltenes' aggregation
چکیده انگلیسی
Temperature dependencies of electron paramagnetic resonance spectra of intrinsic paramagnetic vanadyl complexes and dynamical viscosity for two heavy crude oils and asphalt samples are measured. Transitions between the different motional conditions (from the rigid to the fast motion regimes) are observed. The rotational correlation times (in the model of the isotropic diffusion) are extracted. It is shown that the characteristic temperatures for the motional regime transitions are mainly defined by the asphaltenes' content. From our analysis it follows that the thermal treatment leads to the destruction of the asphaltene complexes onto the 4-5 small pieces. The results indicate that paramagnetic vanadyl complexes are the sensitive intrinsic probes to study qualitatively and quantitatively structural transformations of aspahltenes of heavy crude oils in-situ.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Petroleum Science and Engineering - Volume 166, July 2018, Pages 363-368
نویسندگان
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