کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
8125443 | 1522780 | 2018 | 28 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Molecular simulation of methane adsorption on type II kerogen with the impact of water content
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
علوم زمین و سیارات
زمین شناسی اقتصادی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Based on realistic kerogen model, the effects of water content on methane (CH4) adsorption capacity were studied qualitatively and quantitatively using the molecular dynamics (MD) and Monte Carlo (MC) simulation methods. The methane single component adsorption process under the dry condition, methane and water two components competitive adsorption on dry kerogen, and methane single component adsorption on moist conditions (0.6, 1.2, 1.8, 2.4, and 3.0Â wt%) were simulated. Adsorption processes under different temperatures (298, 323, and 348Â K) were modeled, and the pressure was up to 20Â MPa. Simulation results show that the absolute adsorption capacity of CH4 on the dry kerogen increases with the increasing pressure but decreases with the increasing temperature. The excess adsorption capacity increases up to a specific pressure and then declines with the increasing pressure. The competitive adsorption simulation results indicate that kerogen prefers to adsorb water (H2O) than CH4. At the pressure of 20Â MPa and temperature of 298Â K, the competitive adsorption capacity of CH4 (0.53Â mmol/g) is only a seventh of the single component adsorption capacity of CH4 (3.92Â mmol/g) on dry kerogen. The CH4 adsorption capacity on moist kerogen also decreases with the increasing moist content. Compared with the absolute adsorption capacity on the dry kerogen (3.92Â mmol/g), the adsorption capacity on the moist kerogen reduces about 16%, 30%, 40%, 47%, and 55% at 20Â MPa, respectively. The reduction of the adsorption capacity is attributed to the strong attraction between kerogen and water. At last, the effect of the water content on the shale gas adsorption is discussed under the micro-scale, and the adsorption capacity reduction curves were calculated under the reservoir conditions. The results show that the adsorption capacity of shale gas is significantly affected by water at the economically recoverable depth. The dry condition is considered as the situation of the maximal adsorption capacity of the shale gas reservoir. This study can serve as a reference for better understanding of the transportation and storage mechanism of shale gas under the reservoir conditions.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Petroleum Science and Engineering - Volume 161, February 2018, Pages 302-310
Journal: Journal of Petroleum Science and Engineering - Volume 161, February 2018, Pages 302-310
نویسندگان
Tianyi Zhao, Xiangfang Li, Zhengfu Ning, Huawei Zhao, Meifen Li,