کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
8152211 | 1524449 | 2013 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Noncentrosymmetric mixed-cation borate: Crystal growth, structure and optical properties of Cs2Ca[B4O5(OH)4]2·8H2O
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
فیزیک و نجوم
فیزیک ماده چگال
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Noncentrosymmetric mixed-cation borate: Crystal growth, structure and optical properties of Cs2Ca[B4O5(OH)4]2·8H2O Noncentrosymmetric mixed-cation borate: Crystal growth, structure and optical properties of Cs2Ca[B4O5(OH)4]2·8H2O](/preview/png/8152211.png)
چکیده انگلیسی
A single crystal of the new noncentrosymmetric material Cs2Ca[B4O5(OH)4]2·8H2O has been grown by a slow evaporation method with sizes up to 10Ã10Ã5 mm3 using an aqueous acetone solution as a solvent. The crystal structure of this compound was determined by single crystal X-ray diffraction. It crystallizes in the Orthorhombic space group P212121 with lattice parameters a=11.5158(7) Ã
, b=12.8558(7)Â Ã
, c=16.7976(10)Â Ã
and Z=4. The optical transmittance spectrum was measured on the Cs2Ca[B4O5(OH)4]2·8H2O crystal, which exhibits an absorption edge at about 190 nm in the UV region. The powder second-harmonic generation (SHG) measurement indicates that Cs2Ca[B4O5(OH)4]2·8H2O is phase-matchable and the signal is about half that of a KDP (KH2PO4) standard. Theoretical calculation shows it has moderate birefringence, and identifies the contribution of cations to the optical properties.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Crystal Growth - Volume 380, 1 October 2013, Pages 176-181
Journal: Journal of Crystal Growth - Volume 380, 1 October 2013, Pages 176-181
نویسندگان
Hongwei Huang, Ran He, Wenjiao Yao, Zheshuai Lin, Chuangtian Chen, Yihe Zhang,