کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
8330165 | 1540239 | 2015 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Chromium (VI) detoxification by oxidation and flocculation of exopolysaccharides from Arthrobacter sp. B4
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موضوعات مرتبط
علوم زیستی و بیوفناوری
بیوشیمی، ژنتیک و زیست شناسی مولکولی
زیست شیمی
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چکیده انگلیسی
The exopolysaccharides from Arthrobacter sp. B4 (B4-EPS) exhibited an excellent chromium (VI) (Cr(VI)) removal capability without any pH adjustment, whereby 50 mg Lâ1 of Cr(VI) could be completely removed by 4 g Lâ1 of B4-EPS. The kinetics tests revealed that the first-order rate constant was 8.3 Ã 10â5 sâ1 and the optimal reaction time was 720 min. However, a low initial concentration of Cr(VI) (5-30 mg Lâ1) would accelerate the reaction rate of Cr(VI) removal and shorten reaction time to less than 360 min. Meanwhile, the X-ray photoelectron spectroscopy (XPS) and ultraviolet-visible (UV-vis) spectra indicated that Cr(VI) was reduced to Cr(III) by B4-EPS in accordance with the emergence of the green reaction products. Furthermore, the Fourier transform-infrared spectra (FT-IR) and nuclear magnetic resonance (NMR) showed that carboxyl and hydroxyl groups of B4-EPS contributed to Cr(VI) reduction. Additionally, a feasible scheme for Cr(VI) detoxification by oxidation and flocculation of B4-EPS is presented.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: International Journal of Biological Macromolecules - Volume 81, November 2015, Pages 235-240
Journal: International Journal of Biological Macromolecules - Volume 81, November 2015, Pages 235-240
نویسندگان
Yumei Li, Qiang Li, Yang Fengying, Jie Bao, Zhiheng Hu, Wenwen Zhu, Yueyue Zhao, Zhaodang Lin, Qingsheng Dong,