Highly sensitive detection of hydrogen peroxide based on nanoporous Fe2O3/CoOcomposites

Nanoporous (NP) Fe2O3/CoO composites were straightforwardly fabricated by a simple dealloying strategy. Electron microscopy characterization demonstrates that selectively etching FeCoAl ternary alloy in a low concentration of NaOH solution generates a nanoparticle structure with a typical diameter around 80 nm. Interestingly, these nanoparticles consist of open three-dimensional bicontinuous nanosponge structure with uniform pore and ligament distribution around 10 nm. The resulted sample is confirmed to be a mixture of Fe2O3 and CoO species based on X-ray photoelectron spectroscopy and X-Ray diffraction analysis. Without any activation pretreatment, NP-Fe2O3/CoO composites exhibit excellent electro-oxidation activity toward H2O2, such as an excellent sensing performance in a wide linear sensing region from 0.05 to 4.85 mM H2O2, fast amperometric response (<2 s), and a lower detection limit to 0.1 μM. Along with these attractive features, the as-made composites also behave as a good anti-interference towards glucose, uric acid, dopamine, and ascorbic acid during H2O2 detection. Furthermore, the H2O2 biosensor based on NP-Fe2O3/CoO composites also exhibits excellent long-term stability and reproducibility.

► NP-Fe2O3/CoO composites were fabricated by selectively dealloying of FeCoAl alloy.
► NP-Fe2O3/CoO shows a nanosponge nanoparticle morphology with the size at 10 nm.
► NP-Fe2O3/CoO shows unique sensing performance for H2O2 with lower detection limit.
► NP-Fe2O3/CoO behaves a good anti-interference to glucose, UA, AA, andDA.