Classification and prediction of rice wines with different marked ages by using a voltammetric electronic tongue

A voltammetric electronic tongue (VE-tongue) was developed to discriminate the difference between Chinese rice wines in this research. Three types of Chinese rice wine with different marked ages (1, 3, and 5 years) were classified by the VE-tongue by principal component analysis (PCA) and cluster analysis (CA). The VE-tongue consisted of six working electrodes (gold, silver, platinum, palladium, tungsten, and titanium) in a standard three-electrode configuration. The multi-frequency large amplitude pulse voltammetry (MLAPV), which consisted of four segments of 1 Hz, 10 Hz, 100 Hz, and 1000 Hz, was applied as the potential waveform. The three types of Chinese rice wine could be classified accurately by PCA and CA, and some interesting regularity is shown in the score plots with the help of PCA. Two regression models, partial least squares (PLS) and back-error propagation-artificial neural network (BP–ANN), were used for wine age prediction. The regression results showed that the marked ages of the three types of Chinese rice wine were successfully predicted using PLS and BP–ANN.

► We self-developed a VE-tongue based on six metallic electrodes.
► We used Multi-frequency large amplitude pulse voltammetry as scanning waveforms.
► We first analyzed Chinese rice wine using the six metallic electrodes.