کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
8857929 | 1619277 | 2018 | 11 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Sorption properties of U(VI) and Th(IV) on two-dimensional Molybdenum Disulfide (MoS2) nanosheets: Effects of pH, ionic strength, contact time, humic acids and temperature
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کلمات کلیدی
موضوعات مرتبط
علوم زیستی و بیوفناوری
علوم محیط زیست
شیمی زیست محیطی
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چکیده انگلیسی
Herein, the two-dimensional MoS2 nanosheet was characterized and its performance as an adsorbent for U(VI) and Th(IV) removal from water was evaluated in batch experiments. The results showed that MoS2nanosheets have a thin thickness and few negligible impurities. Both U(VI) and Th(IV) sorption on MoS2were obviously enhanced by high pH and the oxygen-containing group on the surface of MoS2 increased with an increase of pH. However, the sorption was not affected by ionic strength, suggesting that inner-sphere surface complexation dominated the two sorption processes. The removal efficiency of Th(IV) by MoS2 was higher than that of U(VI) in solutions containing different cations and anions. The adsorption equilibrium for U(VI)/Th(IV) was achieved within 2 h and pseudo-second-order equation showed favorable fit. HA significantly increased the uptake of U(VI)/Th(IV) at pH <7.5/6, while decreased the sorption at pH >7.5/6. Freundlich model provided more fit to the equilibrium data than Langmuir model at pH 5.5. The maximum sorption amount of MoS2 for U(VI)/Th(IV) run up to 492.72/454.72 mgâ
gâ1, obviously higher than the amounts of some other materials. The U(VI)/Th(IV) sorption was a spontaneous and endothermic process. All these results suggested the potential applicable value of MoS2 nanosheets in removing U(VI) or Th(IV) from aqueous solutions.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Environmental Technology & Innovation - Volume 11, August 2018, Pages 328-338
Journal: Environmental Technology & Innovation - Volume 11, August 2018, Pages 328-338
نویسندگان
Xue Li, Qian Li, Wensheng Linghu, Runpu Shen, Baoshan Zhao, Lijia Dong, Ahmed Alsaedi, Tasawar Hayat, Jin Wang, Juan Liu,