کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
8863131 1620199 2018 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
A thermodynamical study on the complex formation of Cm(III) with methacrylate
موضوعات مرتبط
مهندسی و علوم پایه علوم زمین و سیارات ژئوشیمی و پترولوژی
پیش نمایش صفحه اول مقاله
A thermodynamical study on the complex formation of Cm(III) with methacrylate
چکیده انگلیسی
Time-resolved laser fluorescence spectroscopy (TRLFS) is used to investigate the complexation of Cm(III) with methacrylate in NaCl solution as a function of the temperature (20-60 °C), ionic strength (0-2.5 mol/kg) and ligand concentration (0-0.2 mol/kg). The aqueous speciation of Cm(III) is obtained by deconvolution of the experimental emission spectra using pure component spectra of all Cm(III) species involved under the given experimental conditions. By applying the specific ion interaction theory (SIT), the temperature-dependent thermodynamic stability constants (log K0n(T), n = 1,2) are determined by extrapolating the conditional stability constants to zero ionic strength. Additionally, the binary ion interaction coefficients (ε(i,j)) for the interaction between Cl− and the complex species [Cm(Meth)n]3−n (n = 1,2) are calculated. The temperature dependency of log K0n in combination with the integrated Van't Hoff equation provides the molal standard reaction enthalpies and entropies (ΔrH0m, ΔrS0m) of the respective complexation reactions confirming that both, the formation of [CmMeth]2+ and [Cm(Meth)2]+ are endothermic and entropy driven. At temperatures ≥70 °C, an additional Cm(III) species is formed that is attributed to the thermically induced polymerization of methacrylate.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Applied Geochemistry - Volume 92, May 2018, Pages 104-109
نویسندگان
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