کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
8881089 | 1624815 | 2017 | 11 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
MALDI-TOF, 13C NMR and FTIR analysis of the cross-linking reaction of condensed tannins by triethyl phosphate
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موضوعات مرتبط
علوم زیستی و بیوفناوری
علوم کشاورزی و بیولوژیک
علوم زراعت و اصلاح نباتات
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Reaction of condensation and cross-linking of catechin monomer as a model of condensed (flavonoid) tannin extracts and of mimosa tannin itself, as well as of resorcinol with triethyl phosphate (TEP) have been investigated. FTIR, solid state CP-MAS 13C NMR, 31P NMR and MALDI-ToF spectroscopy studies revealed that reaction occurs mainly on the C3 of the flavonoid heterocycle ring and on the aromatic C4â² and C5â² carbons of the flavonoids B-ring, while TEP does not appear to react on the A-ring. A difference in the relative proportions of these two reaction sites for tannin and catechin has been noticed. The reactions appear to be dependent on the temperature. According to the thermogravimetric analysis, materials obtained from the reaction of tannin with TEP showed high thermal stability.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Industrial Crops and Products - Volume 95, January 2017, Pages 621-631
Journal: Industrial Crops and Products - Volume 95, January 2017, Pages 621-631
نویسندگان
M.C. Basso, A. Pizzi, J. Polesel Maris, L. Delmotte, B. Colin, Y. Rogaume,