کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
8915674 1641459 2018 53 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
CaCO3 phase diagram studied with Raman spectroscopy at pressures up to 50 GPa and high temperatures and DFT modeling
موضوعات مرتبط
مهندسی و علوم پایه علوم زمین و سیارات فیزیک زمین (ژئو فیزیک)
پیش نمایش صفحه اول مقاله
CaCO3 phase diagram studied with Raman spectroscopy at pressures up to 50 GPa and high temperatures and DFT modeling
چکیده انگلیسی
We revise the high pressure, high temperature phase diagram of CaCO3 using Raman spectroscopy in conjunction with laser heated diamond anvil cell experiments. We confirm numerous aspects of earlier studies, including a recent X-ray diffraction study about the stability field of CaCO3-VII. Our Raman results show that CaCO3-VII is stable in the lower mantle at a depth of 690-1010 km. Our DFT calculations show that the phase transition from aragonite to CaCO3-VII at ≈25 GPa and from CaCO3-VII to post-aragonite at ≈40 GPa are accompanied by density changes of 2% and 3.5%, respectively. Shear sound velocities change by 9% and −12% across the transitions, respectively. Hence, a sufficient amount, at least locally, of CaCO3 in the Earth's mantle can be detectable by an increase of the shear velocity at 690 km and a decrease of the shear velocity at 1010 km depths.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Physics of the Earth and Planetary Interiors - Volume 281, August 2018, Pages 31-45
نویسندگان
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