Monte-Carlo simulations of optical efficiency in luminescent solar concentrators based on all-inorganic perovskite quantum dots

Luminescent solar concentrator (LSC) devices emerge as a promising technology to reduce the cost of electricity generated by photovoltaic solar cells. Here, we demonstrate the detailed fabrication process of non-crystalline LSC prototype devices based on all-inorganic perovskite quantum dots (QDs) for the first time. The as-prepared all-inorganic perovskite QDs show many advantages, such as tunable absorption spectrum over the entire visible spectral region, high photoluminescence (PL) quantum yield (QY) up to 50%, and narrow emission line widths with FWHM (full width at half maximum) of 17-26 nm, which may greatly improve the optical efficiency of LSC prototype devices. On the optimal doping concentrations, Monte Carlo ray-tracing simulations indicate the LSC prototype devices have an extremely high average optical efficiency, which is 1.22% for CsPbCl3 QDs, 5.43% for CsPbBr3 QDs, and 7.39% for CsPbI3 QDs, respectively. We anticipate these potential high-efficiency LSC prototype devices based on perovskite QDs will shed light on future research of large-scale and high-performance LSCs applications.