Influence of upwelling Zechstein sulphate on the concentration and isotope signature of sedimentary sulphides in a fluvioglacial sand aquifer

The latter originated from dissolved Zechstein SO4, which was reduced during upwelling through the organic-rich Tertiary aquiclude. H2S and HS− reacted and precipitated with Fe and other metal ions shortly after migration into the Corg-poor Quaternary aquifer. The sulphides yield valuable information concerning the ascent of confined saline solutions from isolated Zechstein evaporites inside the “Mühlberger Graben”, which is covered by Cenozoic sediments and whose extension and boundaries are therefore not well defined. Only a few locations, close to faults and geological windows, show deep-water admixture sufficiently strong to cause visible changes in hydrochemistry and isotopic ratios of SO4 and DIC directly above the base of the Quaternary. Sulphides showing different origins may possibly be used in other areas to provide information concerning underlying geology and hydrodynamics.