Group duality with the topology of precompact convergence

The Pontryagin-van Kampen (P-vK) duality, defined for topological Abelian groups, is given in terms of the compact-open topology. Polar reflexive spaces, introduced by Köthe, are those locally convex spaces satisfying duality when the dual space is equipped with the precompact-open topology. It is known that the additive groups of polar reflexive spaces satisfy P-vK duality. In this note we consider the duality of topological Abelian groups when the topology of the dual is the precompact-open topology. We characterize the precompact reflexive groups, i.e., topological groups satisfying the group duality defined in terms of the precompact-open topology. As a consequence, we obtain a new characterization of polar reflexive spaces. We also present an example of a space which satisfies P-vK duality and is not polar reflexive. Some of our results respond to questions appearing in the literature.