کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
9522327 | 1634964 | 2005 | 10 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
X-ray diffraction study of phase stability in SiO2 at deep mantle conditions
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
علوم زمین و سیارات
علوم زمین و سیاره ای (عمومی)
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چکیده انگلیسی
The stability of SiO2 phases were examined by X-ray diffraction at pressure up to 131 GPa and temperature > 1300 K, corresponding to Earth's deep lower mantle conditions. Three materials, stishovite, cristobalite, and silica glass were used as starting materials, and an argon pressure-transmitting medium was loaded with the sample for five out of six sets of laser-heated diamond cell experiments. X-ray fluorescent crystals were loaded with the sample to ensure alignment of X-ray beam and heating laser. Our results from three different staring materials indicate that the CaCl2-type phase is the stable phase throughout our studied P-T range. We observe the α-PbO2-type phase for cristobalite starting material at pressures greater than 48 GPa at room temperature. However, this transforms to the CaCl2-type structure upon heating between 72-113 GPa. Transition kinetics and metastability may be important in explaining differences in results reported above 75 GPa, and key experimental variables are discussed.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Earth and Planetary Science Letters - Volume 235, Issues 1â2, 30 June 2005, Pages 273-282
Journal: Earth and Planetary Science Letters - Volume 235, Issues 1â2, 30 June 2005, Pages 273-282
نویسندگان
Sean R. Shieh, Thomas S. Duffy, Guoyin Shen,