کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
9559266 | 1381153 | 2005 | 10 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Synthesis of core-shell polyurethane-polydimethylsiloxane particles in cyclohexane and in supercritical carbon dioxide used as dispersant media: a comparative investigation
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Polyurethane-polydimethylsiloxane particles of tuneable diameter in the range 0.5-5 μm, have been synthesized by step-growth polymerization, both in cyclohexane and in supercritical carbon dioxide (scCO2) used as dispersant media. The feasibility of the polyaddition between ethylene glycol and tolylene-2,4-diisocyanate, selected as monomers, was first demonstrated in cyclohexane, in the presence of hydroxy- or isocyanate-terminated polydimethylsiloxane used as a surfmer. The polymerizations were then carried out in scCO2 at 60 °C and above 200 bar, after the solubility of each reactant has been determined in scCO2, at various pressures and temperatures. Both in cyclohexane and in scCO2, the reaction extent was determined by means of FTIR spectroscopy. The structure and the morphology of the resulting powdery polyurethane-polydimethylsiloxane 'core-shell' material were confirmed by NMR, SEC, TEM and SEM techniques.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polymer - Volume 46, Issue 4, 7 February 2005, Pages 1057-1066
Journal: Polymer - Volume 46, Issue 4, 7 February 2005, Pages 1057-1066
نویسندگان
Pierre Chambon, Eric Cloutet, Henri Cramail, Thierry Tassaing, Marcel Besnard,