کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
9559320 | 1381159 | 2005 | 10 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Enhanced thermal properties of PS nanocomposites formed from montmorillonite treated with a surfactant/cyclodextrin inclusion complex
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
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چکیده انگلیسی
We have prepared polystyrene/clay nanocomposites using an emulsion polymerization technique. The nanocomposites were exfoliated at 3 wt% content of pristine clay relative to the amount of polystyrene (PS). We employed two surfactants for the montmorillonite: cetylpyridinium chloride (CPC) and the CPC/α-CD inclusion complex. Prior to polymerization, each surfactant intercalates into the layers of the pristine clay dispersed in water. The inclusion complex was characterized by X-ray diffraction, 13C CP/MAS NMR spectra, and 1H NMR spectroscopy, and TGA. X-ray powder patterns of the CPC/α-CD complex indicate that the α-CDs units form channels. The 13C CP/MAS NMR spectrum of the complex suggests that a CPC chain is included in the channel formed by the α-CDs. The 1H NMR spectra of the complexes indicate that the stoichiometry of the complexes is 1:2 (i.e. one CPC molecule and two α-CD units). The TGA reveals that the inclusion complex has higher thermal stability relative to the virgin CPC. We employed both X-ray diffraction (XRD) and transmission electron microscopy (TEM) to characterize the structures of the nanocomposites. The value of Tg of the PS component in the nanocomposite is 6 °C higher than that of the virgin PS and its thermal decomposition temperature is 33 °C higher. The CPC/α-CD-treated clay is more effective than is virgin CPC-treated clay at enhancing the thermal stability of polystyrene.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polymer - Volume 46, Issue 3, 26 January 2005, Pages 741-750
Journal: Polymer - Volume 46, Issue 3, 26 January 2005, Pages 741-750
نویسندگان
Ding-Ru Yei, Shiao-Wei Kuo, Huei-Kuan Fu, Feng-Chih Chang,