کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
9560522 | 1381991 | 2005 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Blends of hydroxypropyl methylcellulose and poly(1-vinylpyrrolidone-co-vinyl acetate): Miscibility and thermal stability
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
The miscibility, kinetic parameters, and mechanism associated with the thermal degradation of hydroxypropyl methylcellulose/poly(1-vinylpyrrolidone-co-vinyl acetate) (HPMC/P(VP-co-VAc)) blends, were analysed. The presence of only one glass transition temperature (Tg) in the blend, intermediate between those for the pure polymers, the shift of the bands in the region of 3430Â cmâ1 and the disappearance of the band at 1647Â cmâ1 from the infrared spectra, suggest miscibility between the components. The thermogravimetric curves associated with the temperature of maximum degradation rate (Tmax) indicate a higher thermal stability for the blend with 30% HPMC and for the pure copolymer. This conclusion was supported by the activation energy (E) values which increased to ca. 190 and 170Â kJÂ molâ1 for the blend with 30% HPMC and the pure copolymer, respectively. The E-values for the studied systems suggested a degradation mechanism associated with a random scission of the chain. The FTIR spectra of the solid residues from the thermal degradation reaction of both systems suggest the formation of alcohol and unsaturated hydrocarbons as reaction products. For the HPMC system, CO2, CO, aldehydes, alcohols and ethers were detected as volatile products. Volatile products such as, acetic acid, CO2, CO and NH3 were detected for P(VP-co-VAc).
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polymer Degradation and Stability - Volume 90, Issue 1, October 2005, Pages 21-27
Journal: Polymer Degradation and Stability - Volume 90, Issue 1, October 2005, Pages 21-27
نویسندگان
Cláudia M. Zaccaron, Ricardo V.B. Oliveira, Marcela Guiotoku, Alfredo T.N. Pires, Valdir Soldi,