کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
9560869 1382007 2005 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Effect of UV-irradiation on poly(vinyl chloride) modified by methyl methacrylate-butadiene-styrene copolymer
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
Effect of UV-irradiation on poly(vinyl chloride) modified by methyl methacrylate-butadiene-styrene copolymer
چکیده انگلیسی
The influence of methyl methacrylate-butadiene-styrene copolymer (MBS) on poly(vinyl chloride) (PVC) photodehydrochlorination and photooxidative degradation was investigated by UV-vis, FTIR and fluorescence spectra. The gel amount formed in exposed samples was estimated gravimetrically. It was found that MBS decelerates PVC photodehydrochlorination and photocrosslinking; the effect is caused by the fact that the Cl radicals react with H atoms at tertiary atoms in polystyrene of MBS and initiate the depolymerisation of the PMMA chains of MBS, then leads to reinitiation of PVC dehydrochlorination. The surface free energy of PVC/MBS blends was calculated on the basis of contact angle measurements. The rate of photocrosslinking and photodegradation distinctly influenced the surface free energy, which can reach a maximum value at an appropriate irradiation time.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polymer Degradation and Stability - Volume 87, Issue 3, March 2005, Pages 527-533
نویسندگان
, , ,