کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
9562561 | 1382950 | 2005 | 12 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Removal of caesium catalyst from polyols by ion exchange on Amberlite 252
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
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چکیده انگلیسی
In order to develop an optimized ion exchange process, equilibrium, kinetics, regeneration and final purification of caesium have been studied. A quasi-irreversible equilibrium isotherm was obtained for the system Amberlite 252-Cs in polyol media. The useful capacity of the resin for Cs in polyol media is 3.8Â meq/g. The influence on the exchange rate of the stirring rate, resin to bulk ratio, initial caesium concentration and the type of cation removed have been analyzed. It has been seen that a minimum resin/polyol ratio of 56Â g/kg of polyol is necessary to obtain a suitable exchange rate. Caesium final level in polyol (<5Â mg/kg) is well under the commercial specifications required for this kind of products. Although the removal of caesium ions is slower than the potassium ions and this one slower than sodium, the differences between them are not excessively shown, as expected, that the size of the ion is not so important as the molecular weight of the polyol. The caesium hydroxide after the regeneration process of the resin can be effectively recycled to the process by means of an anion exchange resin.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Reactive and Functional Polymers - Volume 64, Issue 3, September 2005, Pages 139-150
Journal: Reactive and Functional Polymers - Volume 64, Issue 3, September 2005, Pages 139-150
نویسندگان
Mario Pérez-Collado, Carolina Molero, Francisco Larrondo, Paula Sánchez, Lourdes Rodriguez, Juan Francisco RodrÃguez,