کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
9614488 | 48540 | 2005 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Selective single-pot oxidation of cyclohexane by molecular oxygen in presence of bis(maltolato)oxovanadium complexes covalently bonded to carbamated modified silica gel
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
کاتالیزور
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Selective single-pot oxidation of cyclohexane by molecular oxygen in presence of bis(maltolato)oxovanadium complexes covalently bonded to carbamated modified silica gel Selective single-pot oxidation of cyclohexane by molecular oxygen in presence of bis(maltolato)oxovanadium complexes covalently bonded to carbamated modified silica gel](/preview/png/9614488.png)
چکیده انگلیسی
Bis(maltolato)oxovanadium complexes have been covalently bonded to carbamated modified silica gel and shown to act as catalysts for the oxidation of cyclohexane by dioxygen, to cyclohexanol and cyclohexanone with a good activity and selectivity, without any additive and under relatively mild reactions. The effects of various factors were investigated towards the optimization of the reaction conditions and evidence is presented for a free-radical mechanism.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Catalysis A: Chemical - Volume 239, Issues 1â2, 14 September 2005, Pages 96-102
Journal: Journal of Molecular Catalysis A: Chemical - Volume 239, Issues 1â2, 14 September 2005, Pages 96-102
نویسندگان
Gopal S. Mishra, Armando J.L. Pombeiro,