کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
9623703 | 456567 | 2005 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Study of the performance of Pt catalysts supported on activated carbon felt and granular carbon for nitrobenzene hydrogenation
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
The catalytic behavior of the Pt (1Â wt%) catalysts supported on purified activated carbon felt (ACF) and powder carbon (C) has been studied in the nitrobenzene (NBZ) hydrogenation reaction in liquid phase after activation under a H2 atmosphere between 298 and 623Â K. Hydrogen chemisorption measurements, temperature-programmed reduction (TPR) and X-ray photoelectron spectroscopy (XPS) were used to characterize the metallic phase of the catalysts. For Pt/ACF catalysts, the catalytic activity in nitrobenzene hydrogenation after reduction at 298Â K was very high and it decreased as the reduction temperature increased up to 373Â K. On the other hand, the Pt/C catalyst after reduction at 298Â K was inactive. The activity of the Pt/C catalysts increased in a moderate way when the reduction temperature increases up to 373Â K. Between 373 and 623Â K of reduction temperature, the hydrogenation rate was modified in a minor proportion for both catalysts. The Pt/ACF catalyst previously reduced at 298Â K showed a lag step before the reaction ignition. This effect could be attributed to the tendency the metallic centers have to conform the proper arrangement to hydrogenate the nitrobenzene molecule.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chemical Engineering Journal - Volume 114, Issues 1â3, 15 November 2005, Pages 33-38
Journal: Chemical Engineering Journal - Volume 114, Issues 1â3, 15 November 2005, Pages 33-38
نویسندگان
Irene M.J. Vilella, Sergio R. de Miguel, Osvaldo A. Scelza,