کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
9623760 | 456583 | 2005 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Pulp bleaching by hydrogen peroxide activated with copper 2,2â²-dipyridylamine and 4-aminopyridine complexes
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
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چکیده انگلیسی
Oxygen-prebleached kraft pulp (OKP) was bleached with H2O2 activated with a copper complex coordinated with 2,2â²-dipyridylamine (dpa) or 4-aminopyridine (4-ap) under alkaline conditions. Bleaching of OKP by H2O2 activated with the Cu(II)-dpa complex decreased the kappa number (k) and viscosity (v) of the pulp by 26 and 0.7%, respectively. In contrast pulp bleaching without the coordinator resulted in a decrease in k and v values of 25 and 7.8%, respectively. Thus, selectivity for delignification, expressed by k/v, was increased 12-fold by the coordination with dpa. ESR demonstrated that the coordination with dpa suppressed the production of OH by 57%. These results support the involvement of a hydroperoxo complex of Cu(II) formed by the reaction of âOOH with [Cu(II)(dpa)(H2O)3]2+. When the OKP was bleached with H2O2 activated with a Cu(II)-4-ap complex, selectivity (k/v) in pulp bleaching increased by 2.6-fold and production of OH decreased by 47%. We conclude that Cu(II)-dpa is a catalyst potentially applicable to totally chlorine free (TCF) bleaching sequences due to its high selectivity for delignification.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chemical Engineering Journal - Volume 112, Issues 1â3, 1 September 2005, Pages 167-171
Journal: Chemical Engineering Journal - Volume 112, Issues 1â3, 1 September 2005, Pages 167-171
نویسندگان
Noor Rahmawati, Yasunori Ohashi, Yoichi Honda, Masaaki Kuwahara, Karin Fackler, Kurt Messner, Takashi Watanabe,