کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
9625984 460681 2005 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Modification of the nonrandom factor (NRF) model for correlation of the viscosity of polymer solutions
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Modification of the nonrandom factor (NRF) model for correlation of the viscosity of polymer solutions
چکیده انگلیسی
A theory-based model is presented for correlating the viscosity of polymer solutions. The model is based on Eyring's absolute rate theory and the segment-based NRF model for calculating the excess Gibbs energy of activation of the viscous flow. The utility of the model is demonstrated with a successful representation of the viscosity of several polymer solutions. The results show that, the model is valid for the whole range of polymer concentration and it is reliable for correlation of the viscosity of polymer solutions at different polymer molar masses and temperatures. The results are compared with those obtained from the segment-based Eyring-NRTL and segment-based Eyring-Wilson models.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Fluid Phase Equilibria - Volume 232, Issues 1–2, 25 May 2005, Pages 70-73
نویسندگان
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