کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
9633496 | 1426343 | 2005 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Correlation of the osmotic coefficients of the solutions of 1:1 salts in methanol by modified local composition models at 298.15Â K
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موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
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چکیده انگلیسی
Published osmotic coefficient data for the solutions of some 1:1 electrolytes in methanol along with new experimental data for tetramethylguanidinium perchlorate were correlated using local composition models. The studied models are electrolyte non-random two liquid (e-NRTL), non-random factor (NRF), modified NRTL (MNRTL), mean spherical approximation NRTL (MSA-NRTL) and extended Wilson models. In the e-NRTL, NRF, MNRTL and EW models the MSA term was used as the long-range contribution. Results were compared with Pitzer's ion interaction model. All of the models give reliable results.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: The Journal of Chemical Thermodynamics - Volume 37, Issue 11, November 2005, Pages 1177-1185
Journal: The Journal of Chemical Thermodynamics - Volume 37, Issue 11, November 2005, Pages 1177-1185
نویسندگان
Jaber Jahanbin Sardroodi, Moayad Hossaini Sadr, Mohammed Taghi Zafarani-Moattar,