کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
9633599 1426350 2005 11 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Assessment of vapor pressure data of solid metal carbonyls
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Assessment of vapor pressure data of solid metal carbonyls
چکیده انگلیسی
The vapor pressure data of solid metal carbonyls have been assessed and compiled using the “Oonk arc representation” (OAR), also called the “ln f representation”. A simple modification is proposed to the existing OAR called the “modified Oonk arc representation” (MOAR), which aids in the visual representation of the vapor pressure data. The solid metal carbonyls chosen for these data assessment do not exhibit any disproportionation: chromium carbonyl (Cr(CO)6), tungsten carbonyl (W(CO)6), osmium carbonyl (Os3(CO)12), molybdenum carbonyl (Mo(CO)6), rhenium carbonyl (Re2(CO)10), and manganese carbonyl (Mn(CO)5) have been evaluated. The sublimation properties using the assessed data (ΔsubG∘, ΔsubH∘ and ΔsubCp,m∘) of these compounds have been evaluated and a discussion on the mutual consistency of various data sets for each compound over a wide range of temperature is presented.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: The Journal of Chemical Thermodynamics - Volume 37, Issue 4, April 2005, Pages 377-387
نویسندگان
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