کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
9633622 1426352 2005 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Excess molar enthalpies of the ternary mixtures: (methyl tert-butyl ether or 2-methyltetrahydrofuran + cyclohexane + 2,2,4-trimethylpentane) at the temperature 298.15 K
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Excess molar enthalpies of the ternary mixtures: (methyl tert-butyl ether or 2-methyltetrahydrofuran + cyclohexane + 2,2,4-trimethylpentane) at the temperature 298.15 K
چکیده انگلیسی
Measurements of excess molar enthalpies at the temperature T = 298.15 K in a flow microcalorimeter, are reported for the two ternary mixtures {x1(C5H12O or C5H10O) + x2cC6H6 + x3(CH3)2CHCH2C(CH3)3} by mixing component 1 with binary mixtures of components 2 and 3. Smooth representations of the ternary results are presented and used to construct constant excess molar enthalpy contours on Roozeboom diagrams. The application of the Liebermann and Fried model to predict ternary excess enthalpies yielded approximate but correct trend of variation with concentration and the presence of an internal maximum in both ternary systems, using only the physical properties of the components and their binary mixtures.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: The Journal of Chemical Thermodynamics - Volume 37, Issue 2, February 2005, Pages 181-186
نویسندگان
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