کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
9633633 | 1426353 | 2005 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Extension of the Wilson model to multicomponent polymer solutions: applications to polymer-polymer aqueous two-phase systems
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
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چکیده انگلیسی
The Wilson model for non-electrolytes has been extended for the representation of the excess Gibbs energy of multicomponent polymer solutions. The excess Gibbs energy of a polymer solution is expressed as a sum of contributions of a combinatorial and a residual excess Gibbs energy term. The contribution of the combinatorial excess Gibbs energy is represented by the Flory-Huggins expression. A new expression based on the local composition concept, which is a modified Wilson model, has been developed to account for the contribution of the residual excess Gibbs energy. The model has been applied to several polymer-polymer aqueous two-phase systems. The results show that the model is reliable both for correlation and prediction of the liquid-liquid equilibrium phase diagrams of aqueous two-phase systems at different polymer molecular weights.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: The Journal of Chemical Thermodynamics - Volume 37, Issue 1, January 2005, Pages 55-60
Journal: The Journal of Chemical Thermodynamics - Volume 37, Issue 1, January 2005, Pages 55-60
نویسندگان
Rahmat Sadeghi,