کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
9674095 1453197 2005 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Dye adsorption on unburned carbon: Kinetics and equilibrium
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی بهداشت و امنیت شیمی
پیش نمایش صفحه اول مقاله
Dye adsorption on unburned carbon: Kinetics and equilibrium
چکیده انگلیسی
Unburned carbon in fly ash is an important by-product from coal combustion. In this investigation, unburned carbon has been separated from fly ash and been employed as a low cost adsorbent for a basic dye adsorption (Rhodamine B) in aqueous solution. Adsorption isotherm and kinetics of adsorption have been investigated using batch experiments. It is found that dye adsorption capacity depends on initial concentration, pH of solution, and temperature. The adsorption isotherm can be described by Langmuir model and the adsorption capacity of Rhodamine B at 30, 40, and 50 °C can reach 9.7 × 10−5, 1.14 × 10−4, and 1.5 × 10−4 mol g−1, respectively. The pseudo first- and second-order kinetic models have been employed to fit the dynamic adsorption. It is found that the dynamic adsorption follows the pseudo second-order model. Thermodynamic calculations indicate that the adsorption is endothermic reaction with ΔH° at 25 kJ mol−1.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Hazardous Materials - Volume 126, Issues 1–3, 11 November 2005, Pages 71-77
نویسندگان
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