کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
9679019 | 1454616 | 2005 | 10 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Effect of hexafluoropropylene oxide plasma polymer particle coatings on the rheological properties of boron nitride/poly(dimethylsiloxane) composites
دانلود مقاله + سفارش ترجمه
دانلود مقاله ISI انگلیسی
رایگان برای ایرانیان
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
شیمی کلوئیدی و سطحی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Effect of hexafluoropropylene oxide plasma polymer particle coatings on the rheological properties of boron nitride/poly(dimethylsiloxane) composites Effect of hexafluoropropylene oxide plasma polymer particle coatings on the rheological properties of boron nitride/poly(dimethylsiloxane) composites](/preview/png/9679019.png)
چکیده انگلیسی
This work explores the use of conformal nanoscale plasma coatings on the surface of boron nitride (BN) powders to control the rheological properties of BN/poly(dimethylsiloxane) (PDMS) composites. BN particles are conformally coated with hexafluoropropylene oxide (HFPO) in a tumbling RF-plasma reactor. Following the HFPO plasma treatment, XPS evidence indicates the presence of thin coating on the surface of the particles having a F:C ratio of 1.77. Filled BN/PDMS composites are investigated using oscillatory shear rheometry in the concentration range of 0.09-0.41 vol% (Ï). The addition of the plasma treated BN particles to the PDMS matrix reduces the complex viscosity by 40-60% when compared with equally loaded control samples across a broad concentration range. The frequency dependence of the maximum packing fraction (Ïm=0.38-0.42) is also observed for both treated and untreated particles. The maximum packing fraction does not appear to be significantly affected by the conformal plasma polymer treatment. The investigation has shown that the relative dynamic viscosity of the BN/PDMS can be described by the modified Mooney equation.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Colloid and Interface Science - Volume 290, Issue 2, 15 October 2005, Pages 582-591
Journal: Journal of Colloid and Interface Science - Volume 290, Issue 2, 15 October 2005, Pages 582-591
نویسندگان
J.F. Bian, W.R. Lujan, D. Harper-Nixon, H.S. Jeon, D.H. Weinkauf,