کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
9684668 | 1456208 | 2005 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Quaternized polyethersulfone Cardo anion exchange membranes for direct methanol alkaline fuel cells
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
تصفیه و جداسازی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
A novel anion exchange membrane, quaternized polyethersulfone Cardo, was prepared. Polyethersulfone Cardo was chloromethylated with the complex solution of chloromethylether and chloride zinc. Subsequent reaction with trimethylamine and ion exchange with sodium hydroxide yields alkaline anion exchange membrane. The quaternized polyethersulfone Cardo (QPES-C) membrane may be suitable for use in low temperature direct methanol alkaline fuel cells. Ionic conductivity and methanol permeability of such membrane as a function of temperature were investigated. Ionic conductivity of QPES-C membrane in 1 M NaOH solution was 4.1 Ã 10â2 S/cm at room temperature and 9.2 Ã 10â2 S/cm at 70 °C. Methanol permeability of QPES-C membrane was from 5.72 Ã 10â8 to 1.23 Ã 10â7 cm2/s over the temperature range 25-70 °C.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Membrane Science - Volume 262, Issues 1â2, 1 October 2005, Pages 1-4
Journal: Journal of Membrane Science - Volume 262, Issues 1â2, 1 October 2005, Pages 1-4
نویسندگان
Lei Li, Yuxin Wang,