کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
9684718 | 1456210 | 2005 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Preparation of a pinhole-free Pd-Ag membrane on a porous metal support for pure hydrogen separation
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
تصفیه و جداسازی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Preparation of a pinhole-free Pd-Ag membrane on a porous metal support for pure hydrogen separation Preparation of a pinhole-free Pd-Ag membrane on a porous metal support for pure hydrogen separation](/preview/png/9684718.png)
چکیده انگلیسی
A pinhole-free palladium membrane with a thickness of 3 μm has been prepared on the surface of a porous sintered stainless steel tube coated with a thin silver layer as a diffusion barrier. Filling of aluminum hydroxide gel in the surface pores of the tube is effective in preventing defect formation during electroless plating of the palladium layer, while the volume of the hydroxide beneath the membrane decreases greatly upon thermal treatment up to 500 °C. The hydrogen flux at 400-500 °C is reasonably proportional to the pressure difference between the two sides of the membrane. Addition of a 2 μm Pd0.8Ag0.2 alloy layer on the membrane by electroplating does not greatly decrease the hydrogen permeability.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Membrane Science - Volume 260, Issues 1â2, 1 September 2005, Pages 84-89
Journal: Journal of Membrane Science - Volume 260, Issues 1â2, 1 September 2005, Pages 84-89
نویسندگان
Jianhua Tong, Ryuichi Shirai, Yukari Kashima, Yasuyuki Matsumura,