کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
9693992 | 1459636 | 2005 | 12 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
The thermodynamic properties of 1-bromoadamantane in the gaseous state
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
جریان سیال و فرایندهای انتقال
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
The sublimation enthalpy for the compound at T = 303.0 K was measured in a differential heat-conducting microcalorimeter of the Calvet type, ÎsubHm°(303.0K)=71.77±0.31kJmolâ1, which agrees with the value obtained by the effusion measurements, ÎsubHm°(298.1K)=71.6±1.1kJmolâ1, within the experimental errors. The molar thermodynamic functions of 1-bromoadamantane in the ideal gaseous state were calculated by the statistical thermodynamic method. The complete set of the fundamentals necessary for the above calculations was made up from the experimental IR and Raman spectral data and the results of DFT calculations (B3LYP/6-31G*). The enthalpy of formation for 1-bromoadamantane was evaluated in terms of three different approaches. The thermodynamic analysis of some reactions with 1-bromoadamantane was performed.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Thermochimica Acta - Volume 436, Issues 1â2, 1 October 2005, Pages 56-67
Journal: Thermochimica Acta - Volume 436, Issues 1â2, 1 October 2005, Pages 56-67
نویسندگان
Ala B. Bazyleva, Gennady J. Kabo, Yauheni U. Paulechka, Dzmitry H. Zaitsau, Andrey V. Blokhin, Viktor M. Sevruk,