کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
9694079 | 1459639 | 2005 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Finding of an unexpected thermal anomaly at very low temperatures due to water confined within a globular protein, bovine serum albumin
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
جریان سیال و فرایندهای انتقال
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Finding of an unexpected thermal anomaly at very low temperatures due to water confined within a globular protein, bovine serum albumin Finding of an unexpected thermal anomaly at very low temperatures due to water confined within a globular protein, bovine serum albumin](/preview/png/9694079.png)
چکیده انگلیسی
Heat capacities and enthalpy relaxation rates of completely anhydrous bovine serum albumin (BSA) and hydrous BSA with 1.85% (w/w) water were measured by using an adiabatic calorimeter to examine the thermal behavior at low temperatures of a small amount of water left within the globular protein molecule. The heat capacities of the hydrous BSA were larger a little on account of the presence of water molecules. In addition, two new phenomena appeared for the hydrous BSA while not for the anhydrous one: spontaneous exothermic and endothermic effects depending on the pre-cooling rates were observed and interpreted as due to a glass transition. Anomalous behavior of heat capacities was found in 60-140Â K and recognized as potentially originating from a kind of phase transition. It is suggested that the water left a little within the BSA is responsible for both the phenomena occurring at low temperatures.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Thermochimica Acta - Volume 431, Issues 1â2, 15 June 2005, Pages 4-8
Journal: Thermochimica Acta - Volume 431, Issues 1â2, 15 June 2005, Pages 4-8
نویسندگان
Kiyoshi Kawai, Toru Suzuki, Masaharu Oguni,