کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
9760216 | 1498044 | 2005 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Enhancement effect of an adsorbed organic acid on oxygen reduction at various types of activated carbon loaded with platinum
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Enhancement effect of an adsorbed organic acid on oxygen reduction at various types of activated carbon loaded with platinum Enhancement effect of an adsorbed organic acid on oxygen reduction at various types of activated carbon loaded with platinum](/preview/png/9760216.png)
چکیده انگلیسی
We have found that application of activated carbon as a support of platinum in electrocatalysts for polymer electrolyte fuel cells improves the activity for oxygen reduction, especially by using activated carbon with trifluoromethanesulfonic acid adsorbed in the pores. In the present study, we investigated this enhancement effect of the acid for oxygen reduction at activated carbon of various specific surface areas and mean pore diameters. After adsorption of potassium trifluoromethanesulfonate onto the activated carbon loaded with platinum, a catalyst layer was formed from the activated carbon and a polymer electrolyte, followed by replacing the potassium ions with protons. We measured the adsorption isotherms of trifluoromethanesulfonate onto the activated carbons and found that adsorption behavior was dependent on the kind of activated carbon. Electrochemical properties of the layer was evaluated by cyclic voltammetry and by the relationship between electrode potential and oxygen reduction current in perchloric acid solution, supporting the layer on a rotating glassy carbon disk electrode. The properties, and consequently the enhancement effect of the organic acid for oxygen reduction, were clearly dependent on the kind of activated carbon and were explicable based on the pore structure and the adsorption behavior.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Power Sources - Volume 148, 15 September 2005, Pages 1-8
Journal: Journal of Power Sources - Volume 148, 15 September 2005, Pages 1-8
نویسندگان
Jun Maruyama, Ikuo Abe,