Low temperature heat capacity of PuPO4

PuPO4 was prepared successfully by coprecipitation and its heat capacity measured between 5 K and 300 K by a hybrid adiabatic relaxation calorimeter. The standard entropy S0 (298.15 K) of PuPO4 was derived and a semi-empirical method was used to describe the total entropy as the sum of the lattice entropy Slat and the excess entropy Sexs as verified for the iso-electronic lanthanide orthophosphates. Thus the standard entropies of some actinide (III) orthophosphates were estimated.