کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
9803211 | 1516463 | 2005 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Solubility and diffusion of hydrogen in AB2-type Laves phase alloys
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
فلزات و آلیاژها
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Solubility of H2 gas and diffusion of H interstitials were studied in Ti0.1Zr0.9Mn0.9V0.1Fe0.5Ni0.5, (Ti0.1Zr0.9)1.1Mn0.9V0.1Fe0.5Ni0.5 and Ti0.1Zr0.9Mn0.9V0.1Fe0.5Co0.5 alloys with C14 hexagonal structure. Data were taken between 400 and 600â° C, for H2 gas pressures up to 100 mbar and H concentrations up to 0.012âH atoms per host-metal formula unit (solid solution phase). H2 absorption is exothermic, and the partial enthalpy of solution per H atom is â(210±10) and â(248±10) âmeV for the two alloys Ti0.1Zr0.9Mn0.9V0.1Fe0.5Ni0.5 and (Ti0.1Zr0.9)1.1Mn0.9V0.1Fe0.5Ni0.5, respectively. The diffusion coefficient of the H interstitials was determined for all three samples from the kinetics of H2 gas absorption. At 500â° C, the diffusion coefficients are â¼5Ã10â5 âcm2sâ1, with activation energies between 292 and 423âmeV.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Alloys and Compounds - Volumes 404â406, 8 December 2005, Pages 265-268
Journal: Journal of Alloys and Compounds - Volumes 404â406, 8 December 2005, Pages 265-268
نویسندگان
M. Kandavel, S. Ramaprabhu, M. Jung, H. Wipf,