کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
9803695 1516471 2005 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Hydrothermal synthesis and structural characterization of a novel NLO compound, La(MoO2)(OH)(IO3)4
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد فلزات و آلیاژها
پیش نمایش صفحه اول مقاله
Hydrothermal synthesis and structural characterization of a novel NLO compound, La(MoO2)(OH)(IO3)4
چکیده انگلیسی
A novel lanthanum molybdenyl iodate, La(MoO2)(OH)(IO3)4, has been prepared by hydrothermal reactions at 170 °C. The X-ray single-crystal structural analysis showed that it crystallizes in the polar and chiral space group P21 with a = 7.0513(7) Å, b = 14.225(1) Å, c = 7.1206(8) Å, β = 115.653(8)°, Z = 2, R1/wR2=0.0269/0.0608 for 2828 observed reflections, and 191 parameters. La(MoO2)(OH)(IO3)4 contains a complex three-dimensional network formed by eight co-ordinated La3+ cations, strongly distorted octahedral Mo(VI) centers, and bridging iodate anions. Infrared spectra further confirmed the presence of MoO66− and IO3− groups as well as MoOH interactions.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Alloys and Compounds - Volume 396, Issues 1–2, 21 June 2005, Pages 255-259
نویسندگان
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