کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
9822524 | 1519145 | 2005 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Role of the Mg/Al atomic ratio in hydrotalcite-based catalysts for NOx storage/reduction
دانلود مقاله + سفارش ترجمه
دانلود مقاله ISI انگلیسی
رایگان برای ایرانیان
موضوعات مرتبط
مهندسی و علوم پایه
علوم زمین و سیارات
ژئوشیمی و پترولوژی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
1.0 wt.% Pt supported catalysts were prepared by incipient wetness impregnation of Mg-Al supports obtained by thermal decomposition of commercial hydrotalcite-type (HT) precursors with different Mg/Al atomic ratios (1.3, 2.0 and 3.0, respectively) and investigated in the storage-reduction of NOx (NSR). These catalysts showed improved performances in comparison to a Toyota-type Pt-Ba/Al2O3 catalyst at temperatures â¤Â 250 °C. This behaviour can be attributed to the formation of well-dispersed cubic Mg(Al)O mixed oxides, which showed good NOx-storage properties, significantly better than those of the stoichiometric spinel MgAl2O4. Both the catalytic activity and the stability after a hydrothermal treatment of Pt/HT catalysts increased by increasing the Mg/Al atomic ratio, while the analogous Pt/MgO catalyst deactivated almost completely, evidencing the key role of the HT precursor.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Applied Clay Science - Volume 29, Issues 3â4, June 2005, Pages 258-266
Journal: Applied Clay Science - Volume 29, Issues 3â4, June 2005, Pages 258-266
نویسندگان
G. Fornasari, R. Glöckler, M. Livi, A. Vaccari,