Interactions of pendimethalin with organo-montmorillonite complexes

Pendimethalin (PM) is a dinitroaniline herbicide, highly hydrophobic and with a very low solubility in water. It is used for pre-emergence weed control, is usually applied before sowing, and mechanically incorporated into the soil. We tested sorption of PM on montmorillonite and on two different organo-montmorillonites in a mixed water-chloroform environment, to determine the feasibility of developing an environmentally oriented formulation of the herbicide. FTIR measurements show that the interactions of PM with montmorillonite on which difenzoquat (DZ) or mepiquat (MQ) were previously adsorbed are via the nitro and methyl groups of the herbicide. The pre-adsorbed organocations cause a dehydration of the interlayer space, leading to hydrophobicity of the organoclay. Changes in the electrokinetic surface charge of the organoclay, measured using a particle charge detector, confirm these results. The high affinity to PM and the hydrophobic behavior of the used organoclays were also demonstrated in experiments using a mixed chloroform-water environment. The crude clay mineral stayed in the water phase, whereas DZ- and MQ-montmorillonites concentrated in the PM-chloroform phase. Amounts of PM adsorbed to the organoclays using this method were very high (up to 0.65 mol PM kg−1 compound), which suggests a very efficient technology of preparation of herbicide-clay formulations, compared with techniques used in the past for similar herbicide-organoclay compounds. Plant experiments using the organoclay-herbicide formulation with higher amount of active ingredient (based on DZ-clay) demonstrate efficient herbicidal activity with 30% less active ingredient.