کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
9952609 | 1455934 | 2018 | 21 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Supported bicyclic amidine ionic liquids as a potential CO2/N2 separation medium
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موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
تصفیه و جداسازی
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چکیده انگلیسی
Five new room temperature ionic liquids were tested as supported ionic liquid membranes (SILMs) for CO2/N2 separation capability. This series of ionic liquids (ILs) contains bicyclic amidine cations of 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU) or 1,5-diazabicyclo[4.3.0]non-5-ene (DBN) with small alkyl chain substituents. These ILs have been synthesized to examine the effects of cation structure on free volume. Relevant physical and chemical properties have been examined, including CO2 solubility and viscosity. The relationship between fractional free volume and permeability of gases is explored, with an interesting note on solubility. Each cation was paired with two different anions: bis(trifluoromethanesulfonyl)imide and tetracyanoborate, for further investigation of the cation-anion interaction on SILM permeability and selectivity. Three of these new ILs have exceeded Robeson's upper bound for CO2/N2 gas separations.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Membrane Science - Volume 565, 1 November 2018, Pages 203-212
Journal: Journal of Membrane Science - Volume 565, 1 November 2018, Pages 203-212
نویسندگان
Jennifer A. Schott, Chi-Linh Do-Thanh, Shannon M. Mahurin, Ziqi Tian, Nicole C. Onishi, De-en Jiang, Sheng Dai,