Keywords: پارامترهای فعال سازی; Kinetics; Activation parameters; Selenocyclofunctionalization; Triethylamine;
مقالات ISI پارامترهای فعال سازی (ترجمه نشده)
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Keywords: پارامترهای فعال سازی; Affinity polymer membranes; Oriented process; Facilitated extraction; Permeability; Flux; Apparent diffusion coefficient; Association constant; Activation parameters;
Keywords: پارامترهای فعال سازی; Reaction profiles; Variable-temperature kinetics; Global curve-fitting; Activation parameters
Keywords: پارامترهای فعال سازی; Creep; Nanotwin; Activation parameters; HRTEM; Atomistic simulations;
Keywords: پارامترهای فعال سازی; Norfloxacin; Oxidative metabolism; Cetyltrimethylammonium permanganate; Kinetics; Solvent effect; Activation parameters;
Keywords: پارامترهای فعال سازی; Ene reaction; Triazoline dione; Solvent isotope effect; Alkenes; Solvent addition; Activation parameters;
Keywords: پارامترهای فعال سازی; Arylesterase; Paraoxonase; Activation parameters; Integrated Michaelis equation; Product inhibition;
Keywords: پارامترهای فعال سازی; Drug delivery; Electrochemically controlled release; Release kinetics; Activation parameters; Dual stimuli-responsive polymer; Biopolymer-doped polypyrrole;
Volumetric and viscometric study of thiamine hydrochloride, pyridoxine hydrochloride and sodium ascorbate at TÂ =Â (275.15, 277.15 and 279.15)Â K in dilute aqueous solutions
Keywords: پارامترهای فعال سازی; Density; Viscosity; Apparent molar volume; Activation parameters;
Determination and analysis of CO2 capture kinetics and mechanisms on the novel graphene-based adsorbents
Keywords: پارامترهای فعال سازی; Graphene-based adsorbents; CO2 capture; Adsorption kinetic models; Rate-limiting kinetic models; Activation parameters;
In vitro kinetic based adduct formation mechanism of a cytotoxic Pt(II) complex with sulfur containing bio-relevant molecules and a theoretical approach
Keywords: پارامترهای فعال سازی; Pt(II)-S adduct; Kinetics and mechanism; Activation parameters; HOMO-LUMO energy; TD-DFT;
Volumetric, acoustic and viscometric studies of l-histidine in aqueous solutions of non-steroid anti-inflammatory drug ketorolac tromethamine at different temperatures
Keywords: پارامترهای فعال سازی; Apparent molar volume; Apparent molar isentropic compression; Transfer properties; Viscosity B-coefficient; Activation parameters;
Kinetic and mechanistic study of substitution on a cytotoxic PtII complex with biologically relevant thiols and a density functional study
Keywords: پارامترهای فعال سازی; Kinetics and mechanism; Activation parameters; NBO Analysis; TD-DFT; DFT-based descriptors;
Studies on the oxidation of levofloxacin by N-bromosuccinimide in acidic medium and their mechanistic pathway
Keywords: پارامترهای فعال سازی; Levofloxacin; Oxidation; N-bromosuccinimide; Rate laws; Mechanism; Activation parameters;
Ensemble and single-molecule biophysical characterization of D17.4 DNA aptamer–IgE interactions
Keywords: پارامترهای فعال سازی; Aptamer; Molecular recognition; Fluorescence anisotropy; Dissociation kinetics; Electrostatic interactions; Activation parameters
Spectroscopic investigation on kinetics and mechanistic aspects to electron-transfer process into quinolinium dichromate oxidation of a high blood pressure drug captopril in acidic medium
Keywords: پارامترهای فعال سازی; CPL; Kinetics; Mechanism; Polymerization; Ionic strength; Rate constant; Activation parameters;
Controlling time scales for electron transfer through proteins
Keywords: پارامترهای فعال سازی; Copper proteins; Multicopper oxidases; Azurin; Activation parameters; Marcus theory; Pulse radiolysis
A kinetic study of the oxidation of hydrazine by tris(1,10-phenanthroline)iron(III) in acidic medium
Keywords: پارامترهای فعال سازی; Reaction mechanism; Innersphere; Saturation kinetics; Decomposition; Activation parameters
Micro concentrations of Ru(III) used as homogenous catalyst in the oxidation of levothyroxine by N-bromosuccinimide and the mechanistic pathway
Keywords: پارامترهای فعال سازی; LVT; Rate laws; Catalysis; Free radicals; Activation parameters;
The influence of steric hindrance on kinetics and isotope effects in the reaction of 2,2-bis(4-dimethylaminophenyl)-1-nitro-1-(4-nitrophenyl)ethane with DBU base in acetonitrile
Keywords: پارامترهای فعال سازی; Proton transfer; Acid–base equilibrium; Isotope effects; Activation parameters; Nitrophenyl nitroalkanes; Guanidine bases
Catalytic evaluation of dendrimer-templated Pd nanoparticles in the reduction of 4-nitrophenol using Langmuir-Hinshelwood kinetics
Keywords: پارامترهای فعال سازی; Pd nanoparticles; Dendrimer-templated; Hydroxyl terminated PAMAM dendrimer; 4-Nitrophenol reduction; Langmuir-Hinshelwood parameters; Activation parameters;
Quantum mechanical study on the mechanism and kinetics of the cis-to-trans isomerization of [Pd(C6Cl2F3)I(PH3)2]
Keywords: پارامترهای فعال سازی; Cis-to-trans; Palladium; Mechanism; Activation parameters; Density functional theory; Oxidative addition
Synthesis, characterization and X-ray crystal structures of ruthenium polypyridyl and 2-(2′-hydroxyphenyl)-benzoxazole complexes: Reactivity with 1-methylimidazole, purine, glutathione and CT-DNA
Keywords: پارامترهای فعال سازی; Ruthenium terpyridene complexes; Crystal structures; Aqua ligand substitution; Activation parameters; Associative mechanism; Interaction with CT-DNA
Kinetics and time-dependent Langmuir modeling of 4-nitrophenol adsorption onto Mansonia sawdust
Keywords: پارامترهای فعال سازی; Untreated agricultural wastes; Activation parameters; Diffusion processes; Double exponential model; 4-Nitrophenol; Adsorption
Synthesis, crystal structure and VT-NMR study of cis-[PdCl2(CNC6H3Me2-2,6)(PPh3)]
Keywords: پارامترهای فعال سازی; Phosphine/isocyanide mixed ligand complex; Rearrangement equilibrium; VT-NMR study; Activation parameters
Quantum mechanical study on the mechanism and kinetics of the hydrolysis of organopalladium Complex [Pd(CNN)P(OMe)3]+ in low acidity range
Keywords: پارامترهای فعال سازی; Hydrolysis; Organopalladium; Mechanism; Activation parameters; Density functional theory; Solvent effects;
Kinetic investigation on the oxidation of tris(1,10-phenanthroline)iron(II) by oxone: The effect of BSA-SDS interaction
Keywords: پارامترهای فعال سازی; Oxidation of tris(1,10-phenanthroline)iron(II); BSA; BSA-SDS interaction; CAC & CMC of SDS; Denaturation of BSA; Activation parameters;
Fabrication and characterization of a porous gas-evolving anode constituted of lead dioxide microfibers electroformed on a carbon cloth substrate
Keywords: پارامترهای فعال سازی; Porous gas-evolving anode; Lead dioxide microfibers; Solid polymer electrolyte cell; Activation parameters
The impact of variability in the rheological activation parameters on lower-mantle viscosity stratification and its dynamics
Keywords: پارامترهای فعال سازی; Lower-mantle dynamics; Activation parameters; Postperovskite (ppv) phase transition; Lower-mantle rheology; Radiative thermal conductivity; Plume clusters;
Electron donor–acceptor interaction of 3,4-dimethylaniline with 2,3-dicyano-1,4-naphthoquinone
Keywords: پارامترهای فعال سازی; 2,3-Dicyano-1,4-naphthoquinone; 3,4-Dimethylaniline; Charge transfer complex; Spectrophotometry; Activation parameters
Cautionary note: Linewidth effect in dynamic NMR
Keywords: پارامترهای فعال سازی; Dynamic NMR; Diphenylpicrylhydrazine; Hindered rotation; Line-width effect; Activation parameters
Signatures of activation parameters reveal substrate-dependent rate determining steps in polysaccharide turnover by a family 18 chitinase
Keywords: پارامترهای فعال سازی; Glycoside hydrolase; Chitin; Processivity; Activation parameters; Rate determining steps
Dynamic NMR spectroscopy of three 2,2′-dialkyl/aryl-1-picrylhydrazines in liquid solution
Keywords: پارامترهای فعال سازی; Dynamic NMR; Diarylpicrylhydrazine; Dialkylpicrylhydrazine; Hindered rotation; Atropisomers; Activation parameters
Peroxyoxalate-chemiluminescence of Tinopal CBS as a commercially important optical brightener: Mechanistic study and quantification
Keywords: پارامترهای فعال سازی; Peroxyoxalate-chemiluminescence; Bis(2,4,6-trichlorophenyl)oxalate; Hydrogen peroxide; Brightener; Kinetic profile; Activation parameters; PLS modeling;
Thermodynamic studies on the interactions of phenyl salicylate in protic solvents at different temperatures
Keywords: پارامترهای فعال سازی; Phenyl salicylate; Partial molar volume; Activation parameters; Viscosity B-coefficient;
Kinetic and mechanistic aspects of myrcene production via thermal-induced β-pinene rearrangement
Keywords: پارامترهای فعال سازی; Activation parameters; Diradicals; Cyclobutane fragmentation; Kinetic model; Pericyclic reactions
Applications of the zero-order reaction rate model and transition state theory on the intra-particle sintering of an alumina powder by using surface area measurements
Keywords: پارامترهای فعال سازی; Activation parameters; Alumina; Sintering rate; Surface area; Transition state
Volumetric and viscometric behaviour of amino acids in aqueous metal electrolytes solutions at 308 K
Keywords: پارامترهای فعال سازی; Amino acids; Aqueous electrolytes; Apparent molar volume; Viscosity B-coefficient; Activation parameters
A study of chemiluminescence from reaction of bis(2,4,6-trichlorophenyl)oxalate, hydrogen peroxide and an optical brightener 5-(3-anilino-5-chloroanilino)-2-{(E)-2-[4-(3-anilino-5-chloroanilino)-2-sulfophenyl]-1-ethenyl}-1-benzenesulfonic acid
Keywords: پارامترهای فعال سازی; Peroxyoxalate-chemiluminescence; Brightener; H2O2; TCPO; Activation parameters
Synthesis of tris(N,N′-dialkyldithiocarbamato) iron(III) complexes and their thermal decomposition studies by various techniques
Keywords: پارامترهای فعال سازی; Iron(III) dialkyldithiocarbamates; Magnetic moment; Mössbauer spectra; Thermal decomposition; Activation parameters
Computer simulation of interaction of an edge dislocation with a carbon interstitial in α-iron and effects on glide
Keywords: پارامترهای فعال سازی; Dislocation mobility; Carbon diffusion; Iron alloys; Molecular dynamics; Activation parameters
Adsorption kinetics and mechanism of cationic methyl violet and methylene blue dyes onto sepiolite
Keywords: پارامترهای فعال سازی; Sepiolite; Dyes; Adsorption; Adsorption kinetics; Diffusion; Activation parameters
Thermodynamic and transport properties of l-serine and l-threonine in aqueous sodium acetate and magnesium acetate solutions at T = 298.15 K
Keywords: پارامترهای فعال سازی; Apparent molar volume; Apparent molar adiabatic compressibility; Viscosity B-coefficient; Interaction coefficients; Activation parameters; Amino acids; Sodium acetate; Magnesium acetate
Reactivity of some S-bridge containing diphenyl derivatives (sulfides, sulfoxides, sulfones) towards ortho-positronium atoms in dimethylsulfoxide solution
Keywords: پارامترهای فعال سازی; Positron annihilation; Lifetime spectroscopy; S-bridge containing diphenyl derivatives; Substituent effects; Reaction rate constants; Activation parameters;
Advances in the modelling and analysis of complex and industrial processes
Keywords: پارامترهای فعال سازی; Data modelling; Data fitting; Experimental design; Global analysis; Activation parameters; Reaction enthalpies
Enzymatic activity assay of d-hydantoinase by isothermal titration calorimetry. Determination of the thermodynamic activation parameters for the hydrolysis of several substrates
Keywords: پارامترهای فعال سازی; ITC, Isothermal titration calorimetry; kcat, catalytic rate constant; KM, Michaelis constant; Ea, activation energy; LB, Luria Bertani; ΔHm, molar enthalpyd-hydantoinase; Isothermal titration calorimetry; Activity assay; Activation parameters
Effect of magnesium acetate on the volumetric and transport behavior of some amino acids in aqueous solutions at 298.15 K
Keywords: پارامترهای فعال سازی; Apparent molar volume; Viscosity B-coefficient; Interaction coefficients; Activation parameters; Amino acids; Magnesium acetate
Adsorption kinetics of maxilon blue GRL onto sepiolite from aqueous solutions
Keywords: پارامترهای فعال سازی; Sepiolite; Dye; Adsorption; Adsorption isotherms; Adsorption kinetics; Diffusion; Activation parameters
Correlation between creep activation parameters and microscopic dislocation behaviour in γ TiAl alloys
Keywords: پارامترهای فعال سازی; TiAl intermetallic alloys; Creep; Activation parameters; Mixed climb; Stress jumps; Transmission electron microscopy;