کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
10141692 1646072 2018 9 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
A simple approximation for the distribution of ions between charged plates in the weak coupling regime
ترجمه فارسی عنوان
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موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی تئوریک و عملی
چکیده انگلیسی
The solution of the Poisson-Boltzmann equation for counterions confined between two charged plates is known analytically up to a constant, namely, the ion density in the middle of the channel. This quantity is relevant also because it gives access, through the contact theorem, to the osmotic pressure of the system. Here we compare the values of the ion density obtained by numerical and simulation approaches, and report a useful analytic approximation for the weak coupling regime in the absence of added salt, which predicts the value of the ion density in the worst case within 5%. The inclusion of higher order terms in a Laurent expansion can further improve the accuracy, at the expense of simplicity.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Liquids - Volume 271, 1 December 2018, Pages 301-304
نویسندگان
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